Biblioteca Digital

In recent years different electrokinetic cell models for concentrated colloidal suspensions in aqueous electrolyte solutions have been developed. They share some of its premises with the standard electrokinetic model for dilute colloidal suspensions, in particular, neglecting both the specific role of the so-called added counterions (i.e., those released by the particles to the solution as they get charged), and the realistic chemistry of the aqueous solution on such electrokinetic phenomena as electrophoresis and electrical conductivity. These assumptions, while having been accepted for dilute conditions (volume fractions of solids well below 1 %, say), are now questioned when dealing with concentrated suspensions. In this work, we present a general electrokinetic cell model for such kind of systems, including the mentioned effects, and we also carry out a comparative study with the standard treatment (the standard solution only contains the ions that one purposely adds, without ionic contributions from particle charging or water chemistry). We also consider an intermediate model that neglects the realistic aqueous chemistry of the solution but accounts for the correct contribution of the added counterions. The results show the limits of applicability of the classical assumptions and allow one to better understand the relative role of the added counterions and ions stemming from the electrolyte in a realistic aqueous solution...